For privacy session can't be beat. So, whats wrong? Simplex: Leaks your IP and needs the host to be online. Signal: Not decentral Bitchat: Thats more like IRC than DM and its location / relay based. Nostr DM's: Various standards and if done wrong your metadata is very public. That leaves session. Session is completely metadata secure but doesnt persistently store messages server side. Thats a plus and a con. It is decentralized although with a centralized bootstrap. Another one I personally use is Matrix. Element is a nice client for it but if you use Matrix avoid the main orgs server as its subject to UK law. You want a third party one, they all federate. On Matrix whatever homeservers are involved have the metadata but its end to end encrypted.

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Session can be beat I can write so much here but I just wrote alot. Matrix is a bad open spurce chat the ui is nice but the encryption is shit theres tons of metadata leakage & it's funny chats encrypted but reactions arent. Anyone running a homeserver can use those web admin cp guis & see the ip address of anyone from any server. They can see every room you've joined & more. Matrix Element is a mess the only thing I like about it is threads & the media viewer in room settings when you hit upload.